Tokyoite is a rare barium manganese vanadate mineral with the chemical formula: Ba2(Mn3+,Fe3+)OH(VO4)2. It is the manganese analogue of the iron rich gamagarite[2] and the barium analogue of the lead vanadate, brackebuschite.[3]
It occurs in low-grade metamorphosed sedimentary manganese ore deposits[1] associated with hyalophane, braunite and tamaite.[3]
It was first reported for an occurrence in the Shiromaru Mine, Okutama, Tama district, Tokyo Prefecture, Kantō region, Honshu Island, Japan and approved by the IMA in 2003.[2] It has been found in two mines in Italy and one in Japan, for which it was named.
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